Properties of Selected Glycol Ethers†. Glycol ethers are quite stable when proper handling and storage conditions are employed. Hexyl CARBITOL solvent is used in metal deco inks as a slow evaporating solvent providing good flow and leveling. Glycol ethers are selected for specific purposes, suc… Butyl CELLOSOLVE solvent is a recognized inert formulating aid for the compounding of some insecticides and herbicides. As a class of products, CELLOSOLVE and CARBITOL solvents are: This strong solvency leads to the selection of certain CELLOSOLVE and CARBITOL solvents and the alkoxytriglycol glycol ethers for a broad array of end-uses: Members of the CELLOSOLVE and CARBITOL solvent families are also useful chemical intermediates. Solvent in the formulation of polysulfide polymer-polyepoxy resins used as the food-contact surface for dry food. Additive to flume water for washing sugar beets prior to the slicing operation at a level not to exceed 1 ppm. It is an exceptional retarder solvent for lacquers, improving gloss and flow-out. It is an excellent solvent for household and industrial cleaners, rust removers, and disinfectant. Soluble in oil. These characteristics, as well as its high boiling point and low vapor pressure, make it useful for twist setting and yarn and cloth conditioning. Butyl CARBITOL solvent is useful in lacquers, dopes and stamp-pad and printing inks that require a solvent with an extremely low rate of evaporation. Most tested glycol ethers show LC50 / EC50 values above 1000 mg/L. GLYCOL ETHER DB 1. Butyl CELLOSOLVE Solvent (Ethylene Glycol Monobutyl Ether). Hexyl CELLOSOLVE solvent is a high boiling point, slow evaporating solvent with excellent solvency characteristics. – Surface Tension Methoxytriglycol (Triethylene Glycol Monomethyl Ether), Ethoxytriglycol (Triethylene Glycol Monoethyl Ether), Butoxytriglycol (Triethylene Glycol Monobutyl Ether). monobutyl ether . Applications (5) EPA, CFR 797.1400, Fish Acute Toxicity Test, February 1997. Textile printing and dyeing processes utilize CARBITOL solvent to facilitate penetration into fibers and to promote the production of intense, bright shades. Eastman™ EB Acetate (Ethylene Glycol Monobutyl Ether Acetate) is a high boiling glycol ether-ester. Butyl rubber or EPDM can be used for gaskets and packing. This varies based on the type of coating or paint. Formulating with Glycol Ethers Article Hexyl CELLOSOLVE Solvent (Ethylene Glycol Monohexyl Ether). Biodegradation is the percent ratio of evolved CO2 to maximum theoretical CO2, based on organic carbon content of the test substance. Components of adhesives used in articles intended for packaging, transporting or holding foods. Diethylene Glycol Butyl Ether Product Page. Glycol ethers consist of two components, an alcohol and ether. Glycol Ethers are a family of chemicals with key solvent properties used in various and diverse applications. This allows uniform diffusion of the solvent through the film and maximizes appearance and film properties by reducing the occurrence of defects due to solvent-pop and air entrapment. The petroleum industry relies on glycol ether EB as a drilling stabilizer, oil slick dispersant, and in water-based and oil-based fracturing fluids. Methyl CARBITOL solvent offers both excellent solvency and low volatility. Glycol ethers have several applications in industry as lubricants, colorants, and plasticizers. In fabric cleaners, Butyl CELLOSOLVE solvent assists in removing water-soluble stains and aids in brightening the colors of garments. Some commonly used glycol ethers are listed on page 2, along with their abbreviations and chemical names, to help you identify which ones you may be working with. Typically, e-series glycol ethers are found in pharmaceuticals, sunscreens, cosmetics, inks, dyes and water-based paints, while p-series glycol ethers are used in degreasers, cleaners, aerosol paints and adhesives. Mission Models Thinner . OECD 301-B Carbon Dioxide Evolution Biodegradation Testing(1). As a dispersant, it prevents congealing, which aids in the release of gas. DOW Glycol Ether products are produced through continuous processes of selectively reacting an alcohol and ethylene oxide. Butyl CARBITOL Solvent (Diethylene Glycol Monobutyl Ether). Dow requests that the customer read, understand, and comply with the information contained in this publication and the current Material Safety Data Sheet(s). Glycol Ether EB Version 1.11 Revision Date: 09/05/2019 SDS Number: 100000002203 2 / 12 Glycol Ether EB H319 Causes serious eye irritation. Butyl CELLOSOLVE solvent exhibits strong solvency for alkyd, phenolic, nitrocellulose and maleic-modified resins. Product Profiles These solvents typically have a higher boiling point, together with the favorable solvent properties of lower-molecular weight ethers and alcohols. n-butoxyethanol . (6) EPA, CFR 797.1300, Daphnid Acute Toxicity Test, February 1997. Foam in fire extinguishers, oil spill dispersants, asphalt release products, degreasers, and varnish removers are a wide array of products that use glycol ether EB as a solvent. Table 3. 2. Glycol Ethers have been used since the 1960’s as solvents and stabilizers in a variety of personal, household, and industrial products. Because of its limited water solubility and slow evaporation, it can be used in formulations for the silk screen process to prevent premature setting of the ink. Closed containers may explode due to … FDA Status Soluble in acetone. Soluble in ethanol. HAZARDS IDENTIFICATION Emergency Overview Appearance: liquid, colourless WARNING! The product’s mild odor and ability to improve dye penetration make it attractive for non-grain-raising wood stains, spirit-type dyes and textile dye pastes. Temperature. Hexyl CARBITOL solvent has shown excellent performance in cleaning formulation for the removal of greasy soils. This feature can be used to enhance the solvent effect of Butyl CELLOSOLVE solvent in aqueous solutions. CARBITOL solvent is an important solvent in non-grain-raising wood stains and serves as a component of industrial cleaners. – Vapor Pressure Curves Methyl CARBITOL Solvent (Diethylene Glycol Monomethyl Ether). Propyl CELLOSOLVE solvent is useful in printing and other specialized coatings applications. (3) Decomposes at 760 mmHg, boiling point extrapolated. Registration dossier . These solvents typically have a higher boiling point, together with the favorable solvent properties of … Sigma-Aldrich Products are sold exclusively through Sigma-Aldrich, Inc.
The dual functionality present in the CELLOSOLVE and CARBITOL™ solvents and the alkoxytriglycol glycol ethers accounts for their unique solvency properties. When considering the use of any Dow products in a particular application, you should review Dow’s latest Material Safety Data Sheets and ensure that the use you intend can be accomplished safely. Hexyl CARBITOL solvent is useful as a coalescing aid in waterborne emulsion or dispersion coatings. Thousands of industries rely on glycol ether EB. It has found increased use in cleaning formulations because of its good solvency for greasy soils and waxes. Due to the presence of both an ether and a hydroxyl group in the same molecule, these products are miscible in water, as well as most organic solvents. Reproduction of any materials from the site is strictly forbidden without permission. Butyl CELLOSOLVE solvent heightens gloss, improves flow-out and prevents orange-peel formation in lacquers, conventional and high solid coatings. The ether groups introduce additional sites for hydrogen bonding with improved hydrophilic solubility performance. DOW Glycol Ether products can be stored and piped in carbon steel. No specific requirements for continued use, but EPA may issue data call-ins for toxicology data. Due to its slow evaporation and excellent solvency characteristics, Hexyl CARBITOL solvent contributes good flow and leveling to high solids coatings during the drying/curing cycle. (1) Calculated theoretical oxygen demand (THOD) based on complete oxidation of the chemical to carbon dioxide and water. A centrifugal pump is suitable for transfer services. This glycol ether is incorporated in high-bake enamels to contribute desirable flow and gloss characteristics. Glycol Ether (EB) can solvate both water-soluble and hydrophobic materials. It is liable to form peroxides on exposure to air and light. Butyl CARBITOL solvent is a dye solvent used to promote rapid and uniform ink penetration for printing box-board and similar materials. At temperatures above 50°C, it may be possible to decant an aqueous layer from an upper organic layer, thus reducing the organic content of the aqueous waste stream. Glycol Ether DB (Diethylene Glycol Monobutyl Ether) is a colorless liquid that is miscible with water and most organic solvents. Glycol ethers have many uses; these include use as solvents and as an ingredient in cleaning compounds, liquid soaps, and cosmetics. Health Hazards: Irritating to Eyes Safety Hazard: Not classified as FLAMMABLE, but will burn HEALTH HAZARD: Skin Contact: May cause moderate irritation to skin. It attacks some forms of plastics, rubber and coatings. (3) Percent by weight; 75% Hexyl CARBITOL solvent: 25% water (solubility limitations). Since government regulations and use conditions are subject to change, it is the user’s responsibility to determine that this information is appropriate and suitable under current, applicable laws and regulations. MAY BE HARMFUL IF … † The physical property data listed are considered to be typical properties, not specifications. Inert (or occasionally active) ingredients for use in formulations applied to growing crops only up to time of harvest. Surface Tension of Aqueous Solutions for Selected CARBITOL Solvents, Figure 3. Certain glycol ethers are presently cleared under regulations of the United States Food and Drug Administration (FDA) for use in food-related applications. Some brand names for glycol ethers include Cellosolve, R Carbitol, R Dowanol, R and Ektasolve. With over 300 types of glycol ethers, customers are able to select the appropriate chemical with the flame resistance, solubility, and volatility they require. Chemistry Glycol ether lowers the surface tension of products, stabilizing fluids pumped under extremely high pressures. Methyl CARBITOL solvent is suitable for dyes, oils, fats, waxes and resins. If there are no residues that can be considered as additives under these conditions, FDA regulations are not applicable. The Dow Chemical Company is the world’s leading producer of ethylene-oxide-based glycol ethers, both in product-line breadth and total volume produced. According to the nature of alcohol, molecules of this class can be divided into two groups: E series and P series which correspond to ethylene and propylene respectively. Soluble in heptane. Before handling any other products mentioned in the text, you should obtain available product safety information and take necessary steps to ensure safety of use. In use since the 1930s, glycol ethers are solvents that dissolve both water-soluble and hydrophobic substances. NOTE: Dow does not recommend using aluminum, copper, galvanized iron, galvanized steel, Viton elastomers, neoprene or natural rubber with its glycol ethers. Table 2 (continued). These tests were conducted by procedures that follow EPA(4,5,6)/ASTM(7)/ OECD(8) techniques. (2) Pour Point. Heated storage is not normally required. Glycol ethers may be used in any food-related application (such as coatings or printing inks) without regard to specific FDA regulations if subsequent processing steps, such as washing, drying, vaporizing, heating, purging, etc., are adequate to completely remove all traces of the solvent. Ethylene glycol ethers and glycol ether acetates are clear liquids with mild, pleasant odors. LyondellBasell offers a broad line of glycol ethers based on ethylene and propylene. Table 1. Your business can undoubtedly use it as a safe, effective dispersant and solvent as well. (7) Annual Book of ASTM Standards, Water and Environmental Technology, Vol.11.05, (1995). CARBITOL Solvent (Diethylene Glycol Monoethyl Ether). 52, No.10, October 1980. Surface Tension of Aqueous Solutions for Selected Alkoxytriglycols, Figure 4. Ethereal. Eastman EB Solvent (Ethylene Glycol Monobutyl Ether) offers numerous benefits in coating, ink, and cleaner applications. These solvents are widely used paints & coatings, industrial cleaners, and inks. Some typical examples are: Propyl CELLOSOLVE Solvent (Ethylene Glycol Monopropyl Ether). Registration dossier . Liquid. Small quantities of CARBITOL solvent in these mixtures form translucent-to-clear dispersions, in contrast to the usual turbid dispersion that indicates incomplete solubility. They are extensively used as solvents in industrial processes and manufacturing and as thinner and viscosity improving agents in coating processes. Environmental Effects The increased ether functionality of Hexyl CARBITOL solvent provides greater solubility with water than Hexyl CELLOSOLVE solvent. It is an excellent solvent for many coatings resin types, including alkyd, phenolic, maleic, epoxy, and nitrocellulose resins. Glycol Ether DB Safety Data Sheet according to Federal Register / Vol. Glycol Ether EB Safety Data Sheet according to Federal Register / Vol. Additionally, an appropriate desiccant system may be chosen to prevent moisture pickup during storage or turnover of the tank contents. Butyl CARBITOL solvent is used as a solvent in formulating aids for latex paints and as a dispersant for vinyl chloride resins used in organosols. Our blogs contain information on chemicals and food additives, including nutritional supplements, personal care ingredients, sanitation chemicals, and technical-grade chemicals. The alkoxytriglycols are useful as low-volatility components in paint stripping formulations, as dye carriers for textile dye processes, as chemical process solvents and as intermediates for making esters for use as solvents, surfactants and plasticizers. Aquatic toxicity measurements show effects ranging from slightly toxic to relatively nontoxic with tested species, which included fathead minnows and Daphnia Magna. … Ethylene glycol monobutyl ether, more commonly known as glycol ether EB, butoxyethanol, or 2-Butoxyethanol, is an organic compound with the chemical formula BuOC2H4OH with a sweet odor reminiscent of its family line of ethers. Properties of Selected Glycol Ethers†. HAZARDS IDENTIFICATION Appearance and Odor: Clear. (1) Pensky-Martens Closed Cup unless otherwise noted. The linear hexyl portion of Hexyl CELLOSOLVE solvent provides excellent oil solubility characteristics that make it useful in both consumer and industrial cleaner applications. (1) This test method monitors carbon dioxide produced from the biooxidation of molecular carbon in the test substance. Glycol Ether EB has excellent solvency for a variety of resins including acrylic, alkyd, phenolic, epoxy, nitrocellulose and urethane resins. Product Safety UNRESTRICTED—May be shared with anyone. Table 2. Shipping Data Significant differences exist in product toxicity and corresponding exposure levels considered appropriate for different products within the family. (2) Percent by weight; 90% Hexyl CELLOSOLVE solvent: 10% water (solubility limitations). EPA Status Due to the presence of both an ether and a hydroxyl group in the same molecule, these products are miscible in water, as well as most organic solvents, making this group of products ideal for use as resin solvents in the paint and coating industry. Glycol Ether EB is a solvent used in a wide range of industries. Hexyl CARBITOL Solvent (Diethylene Glycol Monohexyl Ether). R Your Right to Know: A product may contain a glycol ether without listing it on the label or in the ingredients. As a solvent, glycol ether is an ingredient in many coatings, including latex paints, resins, lacquers, varnishes, and enamels. Some glycol ethers exhibit an inverse solubility in water at elevated temperatures. (3) EPA/ASTM bioassay procedures were followed in obtaining these values. Measured value determined by chemical oxygen demand procedure published in Standard Methods for the Examination of Water and Wastewater, 18th ed, Am Public Health Assoc., Washington, DC (1992). ApplicationsUsed in a variety of cleaning applications such as household cleaners, industrial cleaners, laundry prewash stain. Site Use Terms
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